Investigation of δ zirconium hydride morphology in a single crystal using quantitative phase field simulations supported by experiments

In light water nuclear reactors, waterside corrosion of the cladding material leads to the production of hydrogen, a fraction of which is picked up by the zirconium cladding and precipitates into brittle hydride particles. These nanoscale hydride particles aggregate into mesoscale hydride clusters. The principal stacking direction of the nanoscale hydrides precipitated in the cladding tube changes from circumferential in the absence of applied stress to radial under circumferential applied stress. A quantitative phase field model has been developed to predict the hydride morphology observed experimentally and identify the mechanisms responsible for nanoscale hydride stacking. The model focuses on nanoscale hydride precipitation in a single zirconium grain with a detailed description of the anisotropic elastic contribution. The model predictions concerning the shape, orientation, and stacking behavior of nanoscale hydride are analyzed and compared with experimental observations. The model accurately accounts for the experimentally observed elongated nanoscale hydride shape and the stacking of hydrides along the basal plane of the hexagonal zirconium matrix. When investigating the role of applied stress in hydride morphology, the model challenges some of the mechanisms previously proposed to explain hydride reorientation. Although hydride reorientation has been hypothesized to be caused by a change in nanoscale hydride shape, the current study shows that these mechanisms are unlikely to occur. Published by Elsevier B.V.

Files

Metadata

Work Title Investigation of δ zirconium hydride morphology in a single crystal using quantitative phase field simulations supported by experiments
Access
Open Access
Creators
  1. P.-C.A. Simon
  2. Larry K. Aagesen
  3. Andrea M. Jokisaari
  4. Long-Qing Chen
  5. Mark R. Daymond
  6. Arthur T. Motta
  7. Michael R. Tonks
Keyword
  1. Microstructure evolution
  2. Zirconium hydrides
  3. Phase field modeling
  4. Experimental comparison
  5. Nuclear materials
License In Copyright (Rights Reserved)
Work Type Article
Publisher
  1. Journal of Nuclear Materials
Publication Date 2021
Publisher Identifier (DOI)
  1. https://doi.org/10.1016/j.jnucmat.2021.153303
Deposited August 11, 2022

Versions

Analytics

Collections

This resource is currently not in any collection.

Work History

Version 1
published

  • Created
  • Updated
  • Added Creator Sandra Elder
  • Added Investigation of δ zirconium hydride morphology in a single crystal using quantitative phase field simulations supported by experiments.pdf
  • Updated Publication Date, License Show Changes
    Publication Date
    • 2021-10
    License
    • https://rightsstatements.org/page/InC/1.0/
  • Published
  • Updated Acknowledgments Show Changes
    Acknowledgments
    • Author list: P.-C.A. Simona, Larry K. Aagesend, Andrea M. Jokisaari, Long-Qing Chen, Mark R. Daymonde, Arthur T. Motta, Michael R. Tonks
  • Updated Keyword, Publisher, Publisher Identifier (DOI), and 1 more Show Changes
    Keyword
    • Microstructure evolution, Zirconium hydrides, Phase field modeling, Experimental comparison, Nuclear materials
    Publisher
    • Journal of Nuclear Materials
    Publisher Identifier (DOI)
    • https://doi.org/10.1016/j.jnucmat.2021.153303
    Publication Date
    • 2021-10
    • 2021
  • Updated Acknowledgments Show Changes
    Acknowledgments
    • Author list: P.-C.A. Simona, Larry K. Aagesend, Andrea M. Jokisaari, Long-Qing Chen, Mark R. Daymonde, Arthur T. Motta, Michael R. Tonks
  • Deleted Creator Sandra Elder
  • Added Creator P.-C.A. Simon
  • Added Creator Larry K. Aagesen
  • Added Creator Andrea M. Jokisaari
  • Added Creator Long-Qing Chen
  • Added Creator Mark R. Daymond
  • Added Creator Arthur T. Motta
  • Added Creator Michael R. Tonks
  • Updated