Rapid water dynamics structures the OH-stretching spectra of solitary water in ionic liquids and dipolar solvents

In a recent study [J. Phys. Chem. B 126, 4584-4598 (2022)], we have used infrared spectroscopy to investigate the solvation and dynamics of solitary water in ionic liquids and dipolar solvents. Complex shapes observed for water OH-stretching bands, common to all high-polarity solvents, were assigned to water in several solvation states. In the present study, classical molecular dynamics simulations of a single water molecule in four ionic liquids and three dipolar solvents were used to test and refine this interpretation. Consistent with past assignments, simulations show solitary water usually donates two hydrogen bonds to distinct solvent molecules. Such symmetrically solvated water produces the primary pair of peaks identified in the OH spectra of water in nearly all solvents. We had further proposed that additional features flanking this main peak are due to asymmetric solvation states, states in which only one OH group makes a hydrogen bond to solvent. Such states were found in significant concentrations in all of the systems simulated. Simulations of the OH stretching spectra using a semiclassical description and the vibrational map developed by Auer and Skinner [J. Chem. Phys. 128, 224511-224512 (2008)] provided semi-quantitative agreement with experiment. Analysis of species-specific spectra confirmed assignment of the additional features in the experimental spectra to asymmetrically solvated water. The simulations also showed that rapid water motions cause a marked motional narrowing compared with the inhomogeneous limit. This narrowing is largely responsible for making the additional features due to minority solvation states manifest in the spectra.

Files

Metadata

Work Title Rapid water dynamics structures the OH-stretching spectra of solitary water in ionic liquids and dipolar solvents
Access
Open Access
Creators
  1. Sourav Palchowdhury
  2. Kallol Mukherjee
  3. Mark Maroncelli
License In Copyright (Rights Reserved)
Work Type Article
Publisher
  1. Journal of Chemical Physics
Publication Date August 28, 2022
Publisher Identifier (DOI)
  1. https://doi.org/10.1063/5.0107348
Deposited October 03, 2022

Versions

Analytics

Collections

This resource is currently not in any collection.

Work History

Version 1
published

  • Created
  • Added OH_Spectra_Isolated_Water_R1.pdf
  • Added OH_Spectra_Isolated_Water_SI_R1.pdf
  • Added Creator Sourav Palchowdhury
  • Added Creator Kallol Mukherjee
  • Added Creator Mark Maroncelli
  • Published
  • Updated